Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing-Shenfu Area     

TAO Chuanqi  WANG Yanbin  LI Yong  NI Xiaoming  GAO Xiangdong 《《地质学报》英文版》2020,94(2):399-408

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.  相似文献   

榍石LA-SF-ICP-MS U-Pb定年及对结晶和封闭温度的指示   总被引：1，自引：0，他引：1  

赵令浩  曾令森  詹秀春  胡明月  袁继海  孙冬阳  张立飞 《岩石学报》2020,36(10):2983-2994

榍石富含U、Th，贫Pb，是U-Pb定年的理想矿物之一。本文采用激光剥蚀-高分辨等离子体质谱建立榍石U-Pb定年方法，采用25~30μm激光斑束，准确测定榍石U-Pb标准样品BLR-1（~1048Ma）、OLT-1（~1014Ma）和Pakistan（~21.4Ma），以及年轻榍石样品（<100Ma）U-Pb年龄，提高了检测准确性和空间分辨率。综合对比共生锆石和榍石U-Pb年龄、榍石颗粒微量元素和U-Pb年龄环带及不同成分岩浆岩（SiO₂含量48.1%~77.0%）中岩浆榍石的结晶温度，结果表明：岩浆演化过程中，榍石具有宽泛的结晶温度（600~900℃，峰值~750℃），主要集中于岩浆演化中晚期结晶，榍石U-Pb同位素封闭温度接近或略低于锆石，因此同一岩浆体系中锆石与榍石的年龄差异可能反映了该熔体较晚达到榍石饱和，而非熔体热演化历史或封闭温度信息。  相似文献   

天山南坡高冰川覆盖率的木扎提河流域水文过程对气候变化的响应   总被引：5，自引：5，他引：0  

赵求东  赵传成  秦艳  苌亚平  王建 《冰川冻土》2020,42(4):1285-1298

木扎提河是天山南坡冰川面积覆盖率最大（48.2%）的河流， 流域径流过程对气候变化极为敏感， 为了合理管理和规划水资源， 确保水资源的可持续利用， 亟需定量评估气候变化对该流域水文过程的影响。以VIC-CAS分布式水文模型为计算平台， 利用实测的径流和两次冰川编目间的冰川面积变化数据开展了模型的多目标参数化校正和验证， 有效提高了模拟结果的“真实性”， 然后通过数值模拟结果结合观测数据定量解析了流域径流的组成、 变化特征及对气候变化的响应机理。结果表明： 木扎提河总径流集中在暖季（5 - 9月）， 占全年总径流量的77.9%， 冰川径流、 融雪径流和降雨径流分别占总径流量的66.6%、 26.4%和7.0%。1971 - 2010年木扎提河流域气温和降水呈显著增加趋势， 由于降水的增加， 降雨和融雪径流均呈增加趋势， 但冰川径流呈现明显减少趋势， 导致总径流呈现下降趋势。在RCP4.5情景下， 未来该流域气温呈现明显升高趋势， 降水表现为微弱下降趋势； 气候变暖后， 更多降水以降雨形式发生， 未来降雨径流将明显增加， 降雪和融雪径流已于20世纪90年代达到峰值， 随后明显减少； 冰川面积将持续萎缩， 冰川径流于21世纪10年代达到拐点， 随后明显减少， 导致河道总径流量也将明显减少。  相似文献   

中国避暑型与避寒型宜人气候的分布特征及差异     

邓粒子  保继刚 《地理研究》2020,39(1):41-52

宜人气候可以分为避暑型和避寒型两种类型,但现有研究鲜有关注国内两类气候的分布特征及差异。本文采用1981—2010年2132个国家气象观测站数据,基于温湿指数、风寒指数和着衣指数计算各个气象站点的气候综合舒适指数,结合协同克里金空间插值方法对全国避暑型和避寒型宜人气候的分布特征进行了研究,并对两类气候的地域差异进行了分析。结果表明：① 中国避暑型气候区包括40°N以北的西北边疆和东北地区、西北中部地区及西南地区三大集中分布区。中国避寒型气候区集中分布在北回归线以南的低纬地区。② 国内夏冬两季的气候不舒适地域广阔,包括环渤海、长三角等经济发达、人口稠密地区,避暑型与避寒型气候资源的开发潜力显著。③ 两类宜人气候呈现明显的地域分离特征,拥有避暑和避寒双重属性的地方极少。④ 国内避寒型气候是稀缺资源,具有垄断性特征;而避暑型气候相对分布广泛,是一种相对遍在性资源。本文不仅丰富了宜人气候分布特征研究的理论成果,而且可为地方气候资源的旅游开发提供科学依据。  相似文献   

Paleogene evolution and demise of the proto‐Paratethys Sea in Central Asia (Tarim and Tajik basins): Role of intensified tectonic activity at ca. 41 Ma     

Mustafa Y. Kaya  Guillaume Dupont‐Nivet  Jean‐Noël Proust  Pierrick Roperch  Laurie Bougeois  Niels Meijer  Joost Frieling  Chiara Fioroni  Sevin zkan Alt&#x;ner  Ezgi Vardar  Natasha Barbolini  Marius Stoica  Jovid Aminov  Mehmut Mamtimin  Guo Zhaojie 《Basin Research》2019,31(3):461-486

The proto‐Paratethys Sea covered a vast area extending from the Mediterranean Tethys to the Tarim Basin in western China during Cretaceous and early Paleogene. Climate modelling and proxy studies suggest that Asian aridification has been governed by westerly moisture modulated by fluctuations of the proto‐Paratethys Sea. Transgressive and regressive episodes of the proto‐Paratethys Sea have been previously recognized but their timing, extent and depositional environments remain poorly constrained. This hampers understanding of their driving mechanisms (tectonic and/or eustatic) and their contribution to Asian aridification. Here, we present a new chronostratigraphic framework based on biostratigraphy and magnetostratigraphy as well as a detailed palaeoenvironmental analysis for the Paleogene proto‐Paratethys Sea incursions in the Tajik and Tarim basins. This enables us to identify the major drivers of marine fluctuations and their potential consequences on Asian aridification. A major regional restriction event, marked by the exceptionally thick (≤ 400 m) shelf evaporites is assigned a Danian‐Selandian age (ca. 63–59 Ma) in the Aertashi Formation. This is followed by the largest recorded proto‐Paratethys Sea incursion with a transgression estimated as early Thanetian (ca. 59–57 Ma) and a regression within the Ypresian (ca. 53–52 Ma), both within the Qimugen Formation. The transgression of the next incursion in the Kalatar and Wulagen formations is now constrained as early Lutetian (ca. 47–46 Ma), whereas its regression in the Bashibulake Formation is constrained as late Lutetian (ca. 41 Ma) and is associated with a drastic increase in both tectonic subsidence and basin infilling. The age of the final and least pronounced sea incursion restricted to the westernmost margin of the Tarim Basin is assigned as Bartonian–Priabonian (ca. 39.7–36.7 Ma). We interpret the long‐term westward retreat of the proto‐Paratethys Sea starting at ca. 41 Ma to be associated with far‐field tectonic effects of the Indo‐Asia collision and Pamir/Tibetan plateau uplift. Short‐term eustatic sea level transgressions are superimposed on this long‐term regression and seem coeval with the transgression events in the other northern Peri‐Tethyan sedimentary provinces for the 1st and 2nd sea incursions. However, the 3rd sea incursion is interpreted as related to tectonism. The transgressive and regressive intervals of the proto‐Paratethys Sea correlate well with the reported humid and arid phases, respectively in the Qaidam and Xining basins, thus demonstrating the role of the proto‐Paratethys Sea as an important moisture source for the Asian interior and its regression as a contributor to Asian aridification.  相似文献   

Effects of current climate,paleo-climate,and habitat heterogeneity in determining biogeographical patterns of evergreen broad-leaved woody plants in China   总被引：1，自引：1，他引：0  

Xu  Yue  Shen  Zehao  Ying  Lingxiao  Zang  Runguo  Jiang  Youxu 《地理学报(英文版)》2019,29(7):1142-1158

Journal of Geographical Sciences - Understanding biogeographic patterns and the mechanisms underlying them has been a main issue in macroecology and biogeography, and has implications for...  相似文献   

Access routes to high mountain huts facing climate-induced environmental changes and adaptive strategies in the Western Alps since the 1990s     

Jacques Mourey  Ludovic Ravanel  Christophe Lambiel  Joël Strecker  Mattia Piccardi 《Norsk geografisk tidsskrift. Norwegian journal of geography》2019,73(4):215-228

ABSTRACT

In the European Alps, high mountain environments are subject to major impacts resulting from climate change, which strongly affect human activities such as mountaineering. The purpose of the study was to examine changes in access routes to 30 high mountain huts in the Western Alps since the 1990s. Data were derived from the use of two different methods, geo-historical studies and a questionnaire, and were used to identify both the climate-related processes affecting the climbing routes and the strategies implemented by public entities, Alpine clubs, guide companies, and hut keepers to maintain acceptable safety and technical conditions. The case studies revealed issues affecting three access routes and the results from the questionnaire showed that the main processes affecting access routes were loss of ice thickness and retreat from the front of the glaciated areas. Commonly, in situ equipment was installed to facilitate access for mountaineers and/or a part of a route was relocated to a safer area. The authors conclude that in most cases, the measures were effective but they were limited by financial, ethical and legal issues, especially in protected or classified areas that could jeopardise their durability and effectiveness.  相似文献   

川藏铁路交通廊道地质调查工程主要进展与成果     

郭长宝  王保弟  刘建康  涂杰楠  张永双  马剑飞  铁永波  韩冰  马鑫  刘峰  李雪  孟文  钟宁  杨志华  吴瑞安 《中国地质调查》2020,7(6):1-12

川藏铁路是我国正在规划建设的重点工程,由于其位于地形地貌和地质构造都极为复杂的青藏高原东部,在铁路规划建设中面临一系列迫切需要解决的关键地质问题: 区域性活动断裂与断错影响、地质灾害、高地应力及其引起的岩爆和大变形、高温热害、断裂带高压水与涌水突泥、高陡边坡稳定性等。为满足技术支撑川藏铁路规划建设、精准服务国家重大战略实施的需要,中国地质调查局部署了“川藏铁路交通廊道地质调查工程”,聚焦制约川藏铁路规划建设的关键问题,充分发挥地质调查工作对国家重大工程规划建设的支撑作用。2019年主要完成铁路沿线1:5万区域地质调查1 350 km²、1:5万地质灾害调查5 000 km²,建设6口大地热流地质参数井、8个地温监测站,完成地应力测量20孔,编制完成11份地质调查专报,提出的大渡河大桥段、理塘车站段、毛垭坝盆地段等线路优化建议/防灾建议被采纳; 首次将1:5 000大比例尺航空物探技术引入复杂山地铁路工程勘察,创新形成千米级超长水平钻孔定向取心钻进技术,实现500 m深的水平孔地应力测量突破等。该工程通过2019年调查研究,全力提升了铁路沿线地质调查程度与精度,并创新了复杂艰险山区重大工程地质问题与探测技术、地质灾害风险防控理论与减灾关键技术,有效支撑服务了川藏铁路规划建设。  相似文献   

MEEMD-Elman神经网络的电离层TEC预报模型     

汤俊  高鑫 《大地测量与地球动力学》2020,40(4):395-399

利用IGS中心提供的不同纬度的电离层TEC值,建立基于改进的集总平均经验模态分解(MEEMD)算法和Elman回归神经网络(ERNN)模型相结合的电离层TEC预报模型。实验结果表明,在低、中、高不同纬度采用本文方法预报5 d电离层TEC的预测值的均方根误差最优可达到0.96 TECu,相对精度最优达到95.4%,精度较EMD-ERNN模型及单一ERNN模型有显著提高。  相似文献   

华南上扬子区深部温度估算及其油气地质意义     

李香兰  刘绍文  徐明  李旭东  郝春艳 《地质学报》2020,94(6):1896-1910

盆地热体制及深部温度估算对油气和区域地热能资源评估具有重要意义。南方上扬子区是海相油气勘探的重要区块,近年来更是我国页岩气勘探的主要选区。然而,由于数据不足及研究目标的分散,该区的盆地热体制特征还有待深化。结合前人已有地热数据,并整合新近开展的稳态测温数据,我们揭示了上扬子区现今地温梯度、大地热流分布特征,继而估算了1000～6000m埋深处的深部地层温度和2套主要古生界海相烃源岩底界面处的温度。结果表明,上扬子区具有中-低温的地热状态,其现今地温梯度和大地热流的范围(平均值)分别为10～74℃/km(24℃/km)和27～118mW/m~2(64mW/m~2),整体上从东北向西南方向递增,呈现出"东北低、西南高"的分布趋势。1000～6000m埋深处估算温度的分布格局与地温梯度及热流的分布趋势基本一致。东北部的鄂西-湘北地区为低温区,中部的四川盆地其大部分为中温区,西南的云南地区为高温区。上扬子区现今地热分布格局受区域差异构造和岩浆作用控制。结合储层温度估算并综合其他油气地质资料,提出川东的石柱-涪陵、川南的威远-自贡-泸州和宜宾-长宁等区的下志留统龙马溪组页岩层系是上扬子区油气勘探有利区带。  相似文献